Spontaneous combustion of coal piles threatens the production and transportation safety of coal mining, which is attracting more and more attention. To understand the underlying physics, conducting pore-scale research on the spontaneous combustion of coal piles is critical. To enable pore-scale research, a pore-scale model of the spontaneous combustion of a coal pile is described, and governing equations are introduced. To understand the competition between airflow, heat–mass transfer, and oxidation reaction, the lattice Boltzmann method (LBM) is utilized, which offers distinct advantages in handling complex pore geometries, multi-physics coupling, and reactive transport at the pore scale. The present model integrates, for the first time in a pore-scale LB framework, airflow driven by thermal buoyancy, convective heat and mass transfer, and Arrhenius-type oxidation kinetics within a realistic coal pile geometry. After the numerical method is validated, the effects of inflowing air velocity, inflowing air temperature, oxygen concentration, and coal particle size are discussed. With an increase in inflowing air velocity, convective heat transfer is enhanced, and the coal pile maximum temperature decreases monotonically. According to the Arrhenius equation, with an increase in the inflowing air temperature and oxygen concentration, the oxidation reaction is accelerated, and the coal pile maximum temperature increases. When the size of the coal particle increases, the oxidation reactive area decreases, and the coal pile maximum temperature decreases, while the steady temperature is not affected.
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